Types of samples that undergo analysis

A sample's Primary Analytical Type and Secondary Analytical Type dictates the type of QC assessment performed on any of its analytical results.

Type of Sample

Primary Analytical Type

Secondary Analytical Type

Description

Client sample

Unknown

N/A

A registered sample.

Client standard

Unknown

Standard

Unknown sample that is also identified as a standard. Would then need links to Sec QCType, Std and StdLot

Client blank

Unknown

Blank

Unknown sample that is also identified as a blank.Would then need links to Sec QCType, Std and StdLot

Duplicate sample

Duplicate

N/A

A sample made from an Unknown sample during sample preparation, to assess the precision (a measure of the ability to reproduce analytical results) of the sampling and sample preparation process.

Replicate sample

Replicate

N/A

A sample made from an Unknown or Duplicate sample during analytical preparation or at point of analysis, to assess the precision of the analytical process.

Standard sample

Standard

N/A

A sample of known specification that is inserted into the group of samples during analytical preparation or at point of analysis, to assess the accuracy (a measure of the bias of the method) of the analytical process.

Standard duplicate matrix

Standard

Duplicate

A set of samples of known specification that is inserted into the group of samples during sample preparation, to assess the accuracy of the sampling and sample preparation process.

Standard replicate matrix

Standard

Replicate

A set of samples of known specification that is inserted into the group of samples during analytical preparation or at point of analysis, to assess the accuracy of the analytical process.

Blank sample

Blank

N/A

A sample of known blank specification that is inserted into the group of samples during analytical preparation or at point of analysis, to assess the calibration state of the analytical instruments.

Blank duplicate matrix

Blank

Duplicate

A set of samples of known blank specification that is inserted into the group of samples during sample preparation, to assess the calibration state of the sample preparation instruments.

 

Blank replicate matrix

Blank

Replicate

A set of samples of known blank specification that is inserted into the group of samples during analytical preparation or at point of analysis, to assess the calibration state of the analytical instruments.

Spike sample

Spike

N/A

A sample comprising of a portion of unknown sample added to a known standard sample that is inserted into the group of samples during analytical preparation or at point of analysis, to assess the analytical method at varying concentrations of analyte.

Spike duplicate matrix

Spike

Duplicate

A set of samples comprising of a portion of unknown sample added to a known standard sample that is inserted into the group of samples during sample preparation, to assess the preparation method at varying concentrations of analyte.

Spike replicate matrix

Spike

Replicate

A set of samples comprising of a portion of unknown sample added to a known standard sample that is inserted into the group of samples during analytical preparation or at point of analysis, to assess the analytical method at varying concentrations of analyte.

Enumerations for the Primary Analytical Type and Secondary Analytical Type

Enumeration

Long Form

Short Form

0

Unknown

UNK

1

Duplicate

DUP

2

Standard

STD

3

Blank

BLK

4

Spike

SPK

5

Replicate

REP

Processes that Create these Different Types of Samples

Process

New Sample/s

Primary Analytical Type

Primary QC Type Code (the sub-type if the Primary Analytical Type)

Secondary Analytical Type

Secondary QC Type Code (the sub-type of the Secondary Analytical Type)

Duplicate Original Sample

Spike Original Sample

Standard Code

Update Sample and change the Secondary Analytical Type to Standard and select the Standard Code and Standard Lot.

S1

Unknown

<empty>

Standard

QC Type where Analytical Type is Standard

<empty>

<empty>

Standard where Type is Standard

Update Sample and change the Secondary Analytical Type to Blank and select the Standard Code and Standard Lot.

S1

Unknown

<empty>

Blank

QC Type where Analytical Type is Blank

<empty>

<empty>

Standard where Type is Blank

Append/Overwrite QC where the QC Mask contains a QC Mask Member where the Analytical Type is Duplicate and the QC Type Code is linked to a QC Type where Type is Duplicate and no Secondary Analytical Type is defined.

Create a Duplicate QC Sample via Workbook CCQCSM.

DS1

Duplicate—set from the QC Mask Member's QC Type Code > QCType.Analytical Type

QC Type where Analytical Type is Duplicate—set from the QC Mask Member's QC Type Code

<empty>

<empty>

Link to Unknown Sample from which it was made

<emtpy>

<empty>

Append/Overwrite QC where the QC Mask contains a QC Mask Member where the Analytical Type is Replicate and the QC Type Code is linked to a QC Type where Type is Replicate and no Secondary Analytical Type is defined.

Create a Replicate QC Sample via Workbook CCQCSM.

RS2

Replicate—set from the QC Mask Member's QC Type Code > QCType.Analytical Type

QC Type where Analytical Type is Replicate—set from the QC Mask Member's QC Type Code

<empty>

<empty>

Link to Unknown Sample or Replicate QC Sample from which it was made

<empty>

<empty>

Append/Overwrite QC where the QC Mask contains a QC Mask Member where the Analytical Type is Standard and the QC Type Code is linked to a QC Type where Type is Standard and no Secondary Analytical Type is defined.

Create a standard QC Sample via Workbook CCQCSM.

STD1

Standard—set from the QC Mask Member's QC Type Code > QCType.Analytical Type

QC Type where Analytical Type is Standard—set from the QC Mask Member's QC Type Code

<empty>

<empty>

<empty>

<empty>

Standard where Type is Standard

Append/Overwrite QC where the QC Mask contains a QC Mask Member where the Analytical Type is Standard and QC Type Code is linked to a QC Type where Type is Standard, and the Secondary Analytical Type is Duplicate, Secondary QC Type Code is linked to a QC Type where Type is also Standard but the Secondary Analytical Type is Duplicate and the Linked QC Type matches the QC Mask Member's QC Type Code and Number to Apply > 1 (thereby having subsequent Sample/s of the same Primary Analytical Type created and linked to the first).

Update Sample and change the Secondary Analytical Type to Duplicate and Secondary QC Type Code and Dup Original Sample Name.

Create a Standard Duplicate QC Sample via Workbook CCQCSM.

STD1DUP

Standard—set from the QC Mask Member's QC Type Code > QCType.Analytical Type

QC Type where Analytical Type is Standard—set from the QC Mask Member's QC Type Code

Duplicate—set from the QC Mask Member's Secondary QC Type Code > QCType.SecondaryAnalyticalType

QC Type where Analytical Type is Standard and Secondary Analytical Type is Duplicate—set from the QC Mask Member's Secondary QC Type Code

Link to standard QC Sample from which it was made—STD1

<empty>

Standard where Type is Standard

Append/Overwrite QC where the QC Mask contains a QC Mask Member where the Analytical Type is Standard and QC Type Code is linked to a QC Type where Type is Standard, and the Secondary Analytical Type is Replicate, Secondary QC Type Code is linked to a QC Type where Type is also Standard but the Secondary Analytical Type is Replicate and the Linked QC Type matches the QC Mask Member's QC Type Code and Number to Apply > 1 (thereby having subsequent Sample/s of the same Primary Analytical Type created and linked to the first).

Update Sample and change the Secondary Analytical Type to Replicate and Secondary QC Type Code and Dup Original Sample Name.

Create a Standard Replicate QC Sample via Workbook CCQCSM.

STD1REP

Standard—set from the QC Mask Member's QC Type Code > QCType.Analytical Type

QC Type where Analytical Type is Standard—set from the QC Mask Member's QC Type Code

Replicate—set from the QC Mask Member's Secondary QC Type Code > QCType.SecondaryAnalyticalType

QC Type where Analytical Type is Standard and Secondary Analytical Type is Replicate—set from the QC Mask Member's Secondary QC Type Code

Link to standard QC Sample from which it was made—STD1

<emtpy>

Standard where Type is Standard

Append/Overwrite QC where the QC Mask contains a QC Mask Member where the Analytical Type is Blank and the QC Type Code is linked to a QC Type where Type is Blank and no Secondary Analytical Type is defined.

Create a standard QC Blank Sample via Workbook CCQCSM.

BLK1

Blank—set from the QC Mask Member's QC Type Code > QCType.Analytical Type

QC Type where Analytical Type is Blank—set from the QC Mask Member's QC Type Code

<empty>

<empty>

<empty>

<empty>

Standard where Type is Blank

Append/Overwrite QC where the QC Mask contains a QC Mask Member where the Analytical Type is Standard and QC Type Code is linked to a QC Type where Type is Standard, and the Secondary Analytical Type is Duplicate, Secondary QC Type Code is linked to a QC Type where Type is also Standard but the Secondary Analytical Type is Duplicate and the Linked QC Type matches the QC Mask Member's QC Type Code and Number to Apply > 1 (thereby having subsequent Sample/s of the same Primary Analytical Type created and linked to the first).

Update Sample and change the Secondary Analytical Type to Duplicate and Secondary QC Type Code and Dup Original Sample Name.

Create a Standard Duplicate QC Sample via Workbook CCQCSM.

BLK1DUP

Blank—set from the QC Mask Member's QC Type Code > QCType.Analytical Type

QC Type where Analytical Type is Blank—set from the QC Mask Member's QC Type Code

Duplicate—set from the QC Mask Member's Secondary QC Type Code > QCType.SecondaryAnalyticalType

QC Type where Analytical Type is Blank and Secondary Analytical Type is Duplicate—set from the QC Mask Member's Secondary QC Type Code

Link to standard QC Sample from which it was made—STD1

<empty>

Standard where Type is Blank

Append/Overwrite QC where the QC Mask contains a QC Mask Member where the Analytical Type is Standard and QC Type Code is linked to a QC Type where Type is Standard, and the Secondary Analytical Type is Replicate, econdary QC Type Code is linked to a QC Type where Type is also Standard but the Secondary Analytical Type is Replicate and the Linked QC Type matches the QC Mask Member's QC Type Code and Number to Apply > 1 (thereby having subsequent Sample/s of the same Primary Analytical Type created and linked to the first).

Update Sample and change the Secondary Analytical Type to Replicate and Secondary QC Type Code and Dup Original Sample Name.

Create a Standard Replicate QC Sample via Workbook CCQCSM.

BLK1REP

Blank—set from the QC Mask Member's QC Type Code > QCType.Analytical Type

QC Type where Analytical Type is Blank—set from the QC Mask Member's QC Type Code

Replicate—set from the QC Mask Member's Secondary QC Type Code > QCType.SecondaryAnalyticalType

QC Type where Analytical Type is Blank and Secondary Analytical Type is Replicate—set from the QC Mask Member's Secondary QC Type Code

Link to standard QC Sample from which it was made—STD1

<empty>

Standard where Type is Blank

Append/Overwrite QC where the QC Mask contains a QC Mask Member where the Analytical Type is Spike and the QC Type Code is linked to a QC Type where Type is Spike and no Secondary Analytical Type is defined.

Create a spike QC Sample via Workbook CCQCSM.

SPK1

Spike—set from the QC Mask Member's QC Type Code > QCType.Analytical Type

QC Type where Analytical Type is Spike—set from the QC Mask Member's QC Type Code

<empty>

<empty>

<empty>

<empty>

Standard where Type is Spike (or Standard if ALLOW_STANDARDS_AS_SPIKE preference is checked)

Append/Overwrite QC where the QC Mask contains a QC Mask Member where the Analytical Type is Spike and QC Type Code is linked to a QC Type where Type is Spike, and the Secondary Analytical Type is Duplicate, Secondary QC Type Code is linked to a QC Type where Type is also Spike but the Secondary Analytical Type is Duplicate and the Linked QC Type matches the QC Mask Member's QC Type Code and Number to Apply > 1 (thereby having subsequent Sample/s of the same Primary Analytical Type created and linked to the first).

Update Sample and change the Secondary Analytical Type to Duplicate and Secondary QC Type Code and Dup Original Sample Name.

Create a Spike Duplicate QC Sample via Workbook CCQCSM.

SPK1DUP

Spike—set from the QC Mask Member's QC Type Code > QCType.Analytical Type

QC Type where Analytical Type is Spike—set from the QC Mask Member's QC Type Code

Duplicate—set from the QC Mask Member's Secondary QC Type Code > QCType.SecondaryAnalyticalType

QC Type where Analytical Type is Spike and Secondary Analytical Type is Duplicate—set from the QC Mask Member's Secondary QC Type Code

Link to spike QC Sample from which it was made—STD1

<empty>

Standard where Type is Spike (or Standard if ALLOW_STANDARDS_AS_SPIKE preference is checked)

Append/Overwrite QC where the QC Mask contains a QC Mask Member where the Analytical Type is Spike and QC Type Code is linked to a QC Type where Type is Spike, and the Secondary Analytical Type is Replicate, Secondary QC Type Code is linked to a QC Type where Type is also Spike but the Secondary Analytical Type is Replicate and the Linked QC Type matches the QC Mask Member's QC Type Code and Number to Apply > 1 (thereby having subsequent Sample/s of the same Primary Analytical Type created and linked to the first).

Update Sample and change the Secondary Analytical Type to Replicate and Secondary QC Type Code and Dup Original Sample Name.

Create a Spike Replicate QC Sample via Workbook CCQCSM.

SPK1REP

Spike—set from the QC Mask Member's QC Type Code > QCType.Analytical Type

QC Type where Analytical Type is Spike—set from the QC Mask Member's QC Type Code

Replicate—set from the QC Mask Member's Secondary QC Type Code > QCType.SecondaryAnalyticalType

QC Type where Analytical Type is Spike and Secondary Analytical Type is Replicate—set from the QC Mask Member's Secondary QC Type Code

Link to spike QC Sample from which it was made—STD1

<empty>

Standard where Type is Spike (or Standard if ALLOW_STANDARDS_AS_SPIKE preference is checked)